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Stainless Steel
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What is Stainless Steel?
In metallurgy, stainless steel is defined as an iron-carbon alloy with a minimum of 11.5 wt% chromium content. Stainless
steel does not stain, corrode or rust as easily as ordinary steel (it "stains less"), but it is not stain-proof. It is also called
corrosion resistant steel when the alloy type and grade are not detailed, particularly in the aviation industry.
There are different grades and surface finishes of stainless steel to suit the environment to which the material will be
subjected in its lifetime. High oxidation-resistance in air at ambient temperature is normally achieved with additions of a
minimum of 13% (by weight) chromium, and up to 26% is used for harsh environments. The chromium forms a passivation
layer of chromium oxide (Cr2O3) when exposed to oxygen. The layer is too thin to be visible, which means that the metal
remains lustrous. It is, however, impervious to water and air, protecting the metal beneath.
In addition, Nitronic alloys (trademark of Armco, Inc.) reduce the tendency to gall through selective alloying with manganes
e and nitrogen. Nickel also contributes to passivation, as do other less commonly used ingredients such as molybdenum
and vanadium.
Types of stainless steel
Austenitic, or 300 series, stainless steels comprise over 70% of total stainless steel production. They contain a maximum
of 0.15% carbon, a minimum of 16% chromium and sufficient nickel and/or manganese to retain an austenitic structure at
all temperatures from the cryogenic region to the melting point of the alloy. A typical composition of 18% chromium and 10%
nickel, commonly known as 18/10 stainless, is often used in flatware. Similarly, 18/0 and 18/8 are also available.
Superaustenitic stainless steels, such as alloy AL-6XN and 254SMO, exhibit great resistance to chloride pitting and crevice
corrosion due to high molybdenum contents (>6%) and nitrogen additions, and the higher nickel content ensures better
resistance to stress-corrosion cracking over the 300 series. The higher alloy content of superaustenitic steels makes them
more expensive. Other steels can offer similar performance at lower cost and are preferred in certain applications.
Ferritic stainless steels are highly corrosion-resistant, but less durable than austenitic grades. They contain between 10.5%
and 27% chromium and very little nickel, if any. Most compositions include molybdenum; some, aluminium or titanium.
Common ferritic grades include 18Cr-2Mo, 26Cr-1Mo, 29Cr-4Mo, and 29Cr-4Mo-2Ni. Martensitic stainless steels are not as
corrosion-resistant as the other two classes but are extremely strong and tough, as well as highly machineable, and can be
hardened by heat treatment. Martensitic stainless steel contains chromium (12-14%), molybdenum (0.2-1%), nickel (0-< 2%),
and carbon (about 0.1-1%) (giving it more hardness but making the material a bit more brittle). It is quenched and magnetic.
It is also known as series-00 steel.
Precipitation-hardening martensitic stainless steels have corrosion resistance comparable to austenitic varieties, but can be
precipitation hardened to even higher strengths than the other martensitic grades. The most common, 17-4PH, uses about 17%
chromium and 4% nickel. There is a rising trend in defense budgets to opt for an ultra-high-strength stainless steel if possible
in new projects, as it is estimated that 2% of the U.S. GDP is spent dealing with corrosion. The Lockheed-Martin Joint Strike
Fighter is the first aircraft to use a precipitation-hardenable stainless steel?Carpenter Custom 465?in its airframe.
Duplex stainless steels have a mixed microstructure of austenite and ferrite, the aim being to produce a 50/50 mix, although
in commercial alloys, the mix may be 40/60 respectively. Duplex steels have improved strength over austenitic stainless steels
and also improved resistance to localised corrosion, particularly pitting, crevice corrosion and stress corrosion cracking.
They are characterised by high chromium (19?28%) and molybdenum (up to 5%) and lower nickel contents than austenitic
stainless steels.
Stainless steel finishes
Grade Ftatures Usages
304
Most widely used steel grade. Good corrosion
resistancd. Themal resistance, low-temperature
strength and mechanical properties. Good drawability
such as deep drawing, bending and does not
harden during heat treatment Non-magnetic.
Facilities in chemical, food and dairy industries,
sinks, interior piping, hot-water boilers, vessel
parts, medical instruments, building materials.
304L
Low carbon Ni-Cr steel, normal conditions, it has
corrosion resistance that is similar to 304 grade.
But, excellent resistance to inter-granular corrosion
after welding and stress relieving.
Machinery and tools used in the chemical coal,
textile, neclear energy and petroleum industry that
required high inter-granular corrosion resistance,
buinding materials, heat resistant parts that are
difficult to implement heat treatment on
316
Excellent corrosion resistance, pitting corrosion
resistance and high temperature strength by adding
Mo & Ni 2~3%. Useful in severe/harsh conditions.
Excellent drawing hardening. Non-magnetic.
Sea water equipment, equipment for chemicals,
paper, dye, acetic acid, fertilizer, photo and food
industry and construction in coastal areas, ropes,
nuts and bolts part.
316L
Low carbon Ni-Cr streel type with adding Mo. It has
the normal properties of 316 grade, but plus excellent
inter-granular corrosion resistance after welding and
stress relieving.
Pulp, paper, chemical fiber, dye, mesh, phosphoric
acid manufacturing facilities.
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