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Stainless Steel |
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What is Stainless Steel? |
In metallurgy, stainless steel is defined as an iron-carbon alloy with a minimum of 11.5 wt% chromium content. Stainless |
steel does not stain, corrode or rust as easily as ordinary steel (it "stains less"), but it is not stain-proof. It is also called |
corrosion resistant steel when the alloy type and grade are not detailed, particularly in the aviation industry. |
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There are different grades and surface finishes of stainless steel to suit the environment to which the material will be |
subjected in its lifetime. High oxidation-resistance in air at ambient temperature is normally achieved with additions of a |
minimum of 13% (by weight) chromium, and up to 26% is used for harsh environments. The chromium forms a passivation |
layer of chromium oxide (Cr2O3) when exposed to oxygen. The layer is too thin to be visible, which means that the metal |
remains lustrous. It is, however, impervious to water and air, protecting the metal beneath. |
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In addition, Nitronic alloys (trademark of Armco, Inc.) reduce the tendency to gall through selective alloying with manganes |
e and nitrogen. Nickel also contributes to passivation, as do other less commonly used ingredients such as molybdenum |
and vanadium. |
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Types of stainless steel |
Austenitic, or 300 series, stainless steels comprise over 70% of total stainless steel production. They contain a maximum |
of 0.15% carbon, a minimum of 16% chromium and sufficient nickel and/or manganese to retain an austenitic structure at |
all temperatures from the cryogenic region to the melting point of the alloy. A typical composition of 18% chromium and 10% |
nickel, commonly known as 18/10 stainless, is often used in flatware. Similarly, 18/0 and 18/8 are also available. |
Superaustenitic stainless steels, such as alloy AL-6XN and 254SMO, exhibit great resistance to chloride pitting and crevice |
corrosion due to high molybdenum contents (>6%) and nitrogen additions, and the higher nickel content ensures better |
resistance to stress-corrosion cracking over the 300 series. The higher alloy content of superaustenitic steels makes them |
more expensive. Other steels can offer similar performance at lower cost and are preferred in certain applications. |
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Ferritic stainless steels are highly corrosion-resistant, but less durable than austenitic grades. They contain between 10.5% |
and 27% chromium and very little nickel, if any. Most compositions include molybdenum; some, aluminium or titanium. |
Common ferritic grades include 18Cr-2Mo, 26Cr-1Mo, 29Cr-4Mo, and 29Cr-4Mo-2Ni. Martensitic stainless steels are not as |
corrosion-resistant as the other two classes but are extremely strong and tough, as well as highly machineable, and can be |
hardened by heat treatment. Martensitic stainless steel contains chromium (12-14%), molybdenum (0.2-1%), nickel (0-< 2%), |
and carbon (about 0.1-1%) (giving it more hardness but making the material a bit more brittle). It is quenched and magnetic. |
It is also known as series-00 steel. |
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Precipitation-hardening martensitic stainless steels have corrosion resistance comparable to austenitic varieties, but can be |
precipitation hardened to even higher strengths than the other martensitic grades. The most common, 17-4PH, uses about 17% |
chromium and 4% nickel. There is a rising trend in defense budgets to opt for an ultra-high-strength stainless steel if possible |
in new projects, as it is estimated that 2% of the U.S. GDP is spent dealing with corrosion. The Lockheed-Martin Joint Strike |
Fighter is the first aircraft to use a precipitation-hardenable stainless steel?Carpenter Custom 465?in its airframe. |
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Duplex stainless steels have a mixed microstructure of austenite and ferrite, the aim being to produce a 50/50 mix, although |
in commercial alloys, the mix may be 40/60 respectively. Duplex steels have improved strength over austenitic stainless steels |
and also improved resistance to localised corrosion, particularly pitting, crevice corrosion and stress corrosion cracking. |
They are characterised by high chromium (19?28%) and molybdenum (up to 5%) and lower nickel contents than austenitic |
stainless steels. |
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Stainless steel finishes |
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Grade |
Ftatures |
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Usages |
304 |
Most widely used steel grade. Good corrosion |
resistancd. Themal resistance, low-temperature |
strength and mechanical properties. Good drawability |
such as deep drawing, bending and does not |
harden during heat treatment Non-magnetic. |
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Facilities in chemical, food and dairy industries, |
sinks, interior piping, hot-water boilers, vessel |
parts, medical instruments, building materials. |
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304L |
Low carbon Ni-Cr steel, normal conditions, it has |
corrosion resistance that is similar to 304 grade. |
But, excellent resistance to inter-granular corrosion |
after welding and stress relieving. |
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Machinery and tools used in the chemical coal, |
textile, neclear energy and petroleum industry that |
required high inter-granular corrosion resistance, |
buinding materials, heat resistant parts that are |
difficult to implement heat treatment on |
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316 |
Excellent corrosion resistance, pitting corrosion |
resistance and high temperature strength by adding |
Mo & Ni 2~3%. Useful in severe/harsh conditions. |
Excellent drawing hardening. Non-magnetic. |
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Sea water equipment, equipment for chemicals, |
paper, dye, acetic acid, fertilizer, photo and food |
industry and construction in coastal areas, ropes, |
nuts and bolts part. |
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316L |
Low carbon Ni-Cr streel type with adding Mo. It has |
the normal properties of 316 grade, but plus excellent |
inter-granular corrosion resistance after welding and |
stress relieving. |
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Pulp, paper, chemical fiber, dye, mesh, phosphoric |
acid manufacturing facilities. |
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